Hi InfoPathY and thank you for posting,
You'll want to use a repeating table or section and default values for your questions.
Add a repeating table with two columns. One column is your question text and the other column is your answer value.
Go to Data->Default Values and add rows for all of the questions and type in the question text in the question text field. Make sure you don't click OK until you or done because it will close the dialog that you must use to enter all of them. :)
Then, when you export to Excel, choose the option to export a table.
Hope that helps! :)