Are you using FormsDesigner for this? Or InfoPath? I would use a promoted property for this. The field gets added to the form first. Then, in InfoPath, if you walk through the publishing wizard (i.e., don't use quick publish) you have the opportunity to add the new field as a promoted property in your library. If you are using FormsViewer, you can add your form fields as promoted properties and modify the form publish location under the "publish" tab. Please let me know if you need additional information! EDITED TO ADD: I see now this is in the FormsViewer forum, so I'll assume you are using FormsViewer :-) Feel free to reach out if you want to schedule a call for a quick walk-through!
Hilary Stoupa
