If you fill out the form manually with multiple users selected in the same people picker, and open the XML with a text editor, you'll see that the pc:Person node actually repeats (see attached screenshot), and I don't think there is going to be any way (outside of code) to get this to behave the way you need it to.... I mean, if you know how many there might be, you might be able to come up with some way to set it with rules - you'd have to include your max # of pc:Person nodes by default, and manually modify the manifest to indicate which one you were setting, and then use substring-before formulas to parse out each ID.... but that would get mighty messy. You write code at all? :)