First, check out this awesome XPath tutorial:
http://www.w3schools.com/xpath/default.aspTo fix your XPath, try this statement instead:
XDocument.UI.Alert(XDocument.DOM.selectSingleNode( "/dfs:myFields/dfs:dataFields/d:NEWJOB/comments").text);
This will get the first comments node from the NEWJOB group. If you are trying to find a particular node in that group (say, if it's repeating) then you will need to use a node test, which you should learn about in the tutorial above.
I hope this helps, good luck!
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Matt Faus
InfoPath Dev Texas
Matt Faus / Microsoft InfoPath MVPQdabra® Software / Streamline data gathering to turn process into knowledge