Yes, just go to Advanced Settings and change to manage content types. Then, publish the old form template (with modified UI) and new form template as content types and link to the library. You will need to promote properties from the template to site columns and map those into the form library. You may also need to relink the old XMLs so that they open. Qdabra has a Modify PI tool that can do this in bulk. The default ShP UI doesn't support relinking XML to content types, but it's easy to manually modify these or use the Qdabra tool which is cheap.