Hey Shoal,
do the following: Go to Start -> Microsoft Office and select the InfoPath application.
From the Window which opens now slect form the left side "Design A Form". No InfoPath is open. On the right side in the task pane select "New form XML Document or Schema", browse to your xml file and follow the instructions of the wizard.
There you go. This should be it to get you started.
Hope it helps.
Listen to Motörhead cos they play Rock'n Roll :)